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22 August Material Type: Notes; Professor: Crans; Class: Modern Organic Chemistry I; Subject: Chemistry; University: Colorado State University; Term: Fall 2011;
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22 August Homework for chapter 1 posted on ramCT Practice exam 1 posted Grade based on 2 exams out of 3 – drop worst exam Homework due Friday Bonds in a tetrahedron are 109.5° apart Carbon-based Chemistry – geometry around Carbon All single bonds – σ Tetrahedral = sp^3 All double bonds – 1 σ, 1 π Trigonal planar = sp^2 All triples bonds – 1 σ, 2 π Linear = sp Lone pairs occupy as much space as bonds Radicals (single electrons) and empty orbitals do not Acidity How do you know which protons “react” (deprotonate)? Brønsted Acid – proton donor Brønsted Base – proton acceptor Lewis Acid – electron acceptor Lewis Base – electron donor HA ↔ H+^ + A-
pKA = -logKA