Solution
Thermodynamics
REX B. McLELLAN
Materials Science Department
Rice University
Houston, Texas
I. Introduction
II.
Formal Relations for Solutions
A. Partial Molar Quantities
B.
The Ideal Solution
C Activities and Activity Coefficients
D.
Integration of the Gibbs-Duhem Equation
E. Temperature Dependence of AGt
III.
Phase Relations
A. Solid-Liquid Equilibrium
B.
Equilibrium with a Gas
C. Solid-Solid Equilibrium
IV. Models for Solid Solutions
A. Infinitely Dilute Solutions
B.
The Zeroth Approximation
C. The First-Order Approximation
D.
Second-Order Approximations
E. Effects due to Volume Changes
V. Models for Liquid Solutions
A. The Parabolic Formalism
B.
The Quasi-chemical Approach
VI.
Hydrogen-Metal Solutions
A. Data Correlations
B.
Location of H Atoms in Metals
C. Statistical Models
References
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