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Filter Systems - Geochemistry I - Lecture Slides, Slides of Geochemistry

In these Lecture Slides, the Lecturer has tried to illustrate he following points : Filter Systems, Tested, Description, Designation, Ion Chromatography, Acrodisc, Supor Membrane, Acrodisc, Fibre Prefilter, Polypropylene

Typology: Slides

2012/2013

Uploaded on 07/23/2013

sharath_69
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Millex-LS 5 µm prefilter or
Milles-SV
M-3-S
Millex, HN nylon
M-4-S
Millex HV, hydrophilic
Durapore
M-2-S
Sterivex capsule, hydrophilic
Durapore (polyvinylidene
fluoride, PDVF)
M-1-S
GHP Acrodisc, hydrophilic
polypropylene
G-3-S
Acrodisc GF, nylon with glass
fibre prefilter
G-2-S
Ion chromatography Acrodisc,
Supor membrane
G-1-S
DescriptionDesignation
Filter Systems (0.45 µm) tested (12 in total)
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pf4
pf5
pf8
pf9
pfa

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Millex-LS 5 μm prefilter or

Milles-SV

M-3-S

Millex, HN nylon

M-4-S

Millex HV, hydrophilic

Durapore

M-2-S

Sterivex capsule, hydrophilic

Durapore (polyvinylidene

fluoride, PDVF)

M-1-S

GHP Acrodisc, hydrophilic

polypropylene

G-3-S

Acrodisc GF, nylon with glass

fibre prefilter

G-2-S

Ion chromatography Acrodisc,

Supor membrane

G-1-S Designation Description Filter Systems (0.45 μm) tested (12 in total)

Recommended:Recommended: WhatmanWhatman all-plastic syringeall-plastic syringe with Millipore with Millipore DuraporeDurapore Capsule (M-1-S)Capsule (M-1-S) or or MillexMillex Membrane (M-2-S) and HDPE bottleMembrane (M-2-S) and HDPE bottle

Acidification impractical inAcidification impractical in

the field the field……....

• Sampled 5 local rivers/streams,

filtered and created acidified (0.4%

HNO

3

) and unacidified subsets

• Tested element recovery in samples

acidified after 2 months of storage and

then left for 7 days in original bottle

• Used different [HNO

3

] of 0.4, 1, 2, 5,

• Used HDPE, PP, FEP, PET, all in

triplicate

Elements not lost from any sampleElements not lost from any sample over 2-month period include: over 2-month period include: B, Ba, Ca, K, Li, Mg, Mo, Na, Ni, Rb, S, Sb, Si, Sr, U, V Elements with greatest loss over Elements with greatest loss over 2-month period include: 2-month period include: Mn, Fe, Al, Ti, Pb, REEs, Cu, Zn

Pb Rideau River Bottle Type HDPE PP FEP PET Recovery (^) **(%) 0 20 40 60 80 100 120 140 Unacidified

  1. 4 % < 1 Day
  2. 4 % 7 Days 1 % 7 Days 2 % 7 Days 5 % 7 Days 10 % 7 Days
  3. 4 % 127 Days 60 ppt DL 10 ppt**

Recovery of Mn, % 0 20 40 60 80 100 120 140 No a cid Acid [Mn] ranges from 0. 1 to 317 ppb

Pyrolysis/IC for F, Cl, Br, I, S -~100 mg of sample -Several min of pyrolysis time, ~15 min analytical

- DLs in order of 0.5 ppm