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Two problems from a university course on physics applied to pharmacy. The first problem deals with calculating the percentage of a cubic object that is submerged in a liquid based on its mass and the liquid's density. The second problem involves calculating the efficiency and entropy change of a stirling cycle using ideal gas laws.
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Facultat de Farmàcia Departament de Fisicoquímica
GRUP: T 2 PROFESSOR: Joan Estelrich
2
2
3 3 V a 8 m.
2 w mg 4000 kg 9,8 m s 39.200 N.
3 cos cos (^3 )
4 m. 1000 kg m 9,8 m s
B V (^) f f g V (^) fg V (^)
' 3 cos (^3 )
4,1 m. 1000 kg m 9,8 m s
1 1 ln 0,5 mol 8,314 J K mol 900 K ln 2 2.593,27 J.
f A B i
dV^ V w PdV nRT nRT V V
qA (^) B 2.593,27 J.
1 1 qB (^) C qV nCV m (^) , T 0,5 mol 1,5 8,314 J K mol 300 900 K 3.741,3 J.
^ ^ ^ ^ ^ ^ ^
1 1 ln 0,5 mol 8,314 J K mol 300 Kln0,5 864,42 J.
f C D i
w PdV nRT V
qC (^) D 864,42 J.
1 1 qD (^) A qV nCV m (^) , T 0,5 mol 1,5 8,314 J K mol 900 300 K 3.741,3 J.
^ ^ ^ ^ ^ ^ ^
fet
abs
w
q
1 1 1 900 K 300 K
ln ln
ln 0,500 mol 1,5 8,314 J K mol ln 6,85 J K 900
f f V i i
f V i
S nC nR T V
T S nC T