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University Chemistry from the University of the Philippines. This study notes was prepared by a BSCE student on June 2025
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Chem 18 Module 1.3: Electronic Structure of the Atom and Atomic Properties Periodic Trends Periodicity- The elements in the periodic table are so arranged that their properties are periodic functions of their atomic numbers. The Modern Periodic Law: The chemical properties of the elements are periodic functions of their atomic numbers. Effective Nuclear Charge
where: Z = nuclear charge (atomic number, number of protons)
Remember: Valence electrons- outer electrons Core electrons- inner electrons Effective nuclear charge (Zeff) dictates the trends in the Periodic Table high Zeff, stronger attraction of nucleus to the electrons the “ positive charge ” felt by an electron
Atomic radius- Distance between 2 nuclei Atomic Size Ionic size Cation is always smaller than atom from which it is formed. Anion is always larger than atom from which it is formed. Isoelectric ions- The higher the atomic number,,,, smaller radius,,,, smaller ionic size Ionization Energy (IE)