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Electronic Structure of the Atom and Atomic Properties, Study notes of Chemistry

University Chemistry from the University of the Philippines. This study notes was prepared by a BSCE student on June 2025

Typology: Study notes

2024/2025

Available from 06/23/2025

char-maine-j
char-maine-j 🇵🇭

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Chem 18 Module 1.3: Electronic Structure of the Atom and Atomic
Properties
Periodic Trends
Periodicity- The elements in the periodic table are so arranged that their
properties are periodic functions of their atomic numbers.
The Modern Periodic Law: The chemical properties of the elements are
periodic functions of their atomic numbers.
Effective Nuclear Charge
Zeff = Z -
where:
Z = nuclear charge (atomic number, number of protons)
= shielding constant / Inner (core) electrons / Noble gas
Remember:
Valence electrons- outer elec trons
Core electrons - inner electrons
Effective nuclear charge (Zeff)
dictates the trends in the Periodic Table
high Zeff, stronger attraction of nucleus to the electrons
the positive charge felt by an electron
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Chem 18 Module 1.3: Electronic Structure of the Atom and Atomic Properties Periodic Trends Periodicity- The elements in the periodic table are so arranged that their properties are periodic functions of their atomic numbers. The Modern Periodic Law: The chemical properties of the elements are periodic functions of their atomic numbers. Effective Nuclear Charge

Zeff = Z - 

where: Z = nuclear charge (atomic number, number of protons)

 = shielding constant / Inner (core) electrons / Noble gas

Remember: Valence electrons- outer electrons Core electrons- inner electrons Effective nuclear charge (Zeff)  dictates the trends in the Periodic Table  high Zeff, stronger attraction of nucleus to the electrons  the positive charge felt by an electron

Atomic radius- Distance between 2 nuclei Atomic Size Ionic sizeCation is always smaller than atom from which it is formed.  Anion is always larger than atom from which it is formed.  Isoelectric ions- The higher the atomic number,,,, smaller radius,,,, smaller ionic size Ionization Energy (IE)

  • the energy required to completely remove an electron from a gaseous atom or ion - also called ionization potential _- removal of electrons in succession
  • The outermost electrons (least tightly bound) are the ones that_ are removed first Al → Al +^ + 1e-^ IE1= 580 kJ/mol Al+^ → Al 2+^ + 1e-^ IE2 = 1815 kJ/mol Al2+^ → Al 3+^ + 1e-^ IE3 = 2740 kJ/mol Al3+^ → Al 4+^ + 1e-^ IE4 = 11600 kJ/mol IE 1 < IE 2 <IE 3  the closer and more tightly bound an electron is to the nucleus  the more difficult it will be to remove  the higher its ionization energy