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Chemistry - Module 1, Lecture notes of Chemistry

It is about the fundamentals of chemistry like work, heat, and energy.

Typology: Lecture notes

2022/2023

Uploaded on 01/30/2024

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CHEMISTRY FOR ENGINEERS (LECTURE)
Module 1 / First Semester
Ms. Ma. Junallie E. Fuentebella-Pomperada
WORK, MECHANICAL ENERGY AND HEAT
Energy โ€“ capacity to do work or transfer heat
Work โ€“ the energy used to cause an object to move against a force
Heat โ€“ energy used to cause the temperature of an object to increase
WORK
- a scalar quantity (do not have directions)
- defined and measured by the product of the net force
exerted and the distance through which force moves
Formula:
๐‘พ = ๐‘ญ๐’…๐’„๐’๐’”๐œฝ
where W = work
F = force
d = displacement
๐œƒ = angle between the force and the
direction of motion
Joule (J) โ€“ common unit for work
Conversion:
๐Ÿ๐‘ฑ = ๐‘ต โˆ™ ๐’Ž or ๐Ÿ๐‘ฑ = ๐Ÿ ๐’Œ๐’ˆ โˆ™ ๐’Ž/๐’Ž โˆ™ ๐’”๐Ÿ
MECHANICAL ENERGY
- the sum of an objectโ€™s kinetic and potential energy
KINETIC ENERGY
- known as โ€œenergy of motionโ€
- the KE of a body is dependent on its mass and speed
Formula:
๐‘ฒ๐‘ฌ = ๐Ÿ๐Ÿ
โ„๐’Ž๐’—๐Ÿ
where KE = Kinetic Energy
m = mass
v = speed
Note:
1. The kinetic energy of a body increases as its speed
increases. Kinetic Energy (KE) is directly proportional to
Speed (v).
โ€ข A ball rolling at 10m/s has greater kinetic energy
than it does at 5 m/s.
2. For given speed, the kinetic energy increases with increasing
mass.
โ€ข A large truck traveling at 50 km/h has greater
kinetic energy than a small car traveling at the
same speed because the truck has the greater
mass.
Joule (J) โ€“ common unit for Kinetic Energy (KE)
Potential Energy
- known as โ€œenergy due to positionโ€
- an object has potential energy by virtue of its position
relative to other objects
- in essence, the โ€œstoredโ€ energy that arises from the
attractions and repulsions an object experiences in relation
to other objects
Formula: ๐‘ท๐‘ฌ = ๐’Ž๐’ˆ๐’‰
where PE = potential energy
m = mass
g = gravitational acceleration (9.8 m/s2)
h = height
Joule (J) โ€“ common unit for Potential Energy (PE)
Note:
1. Potential energy may be converted into kinetic energy
and vice versa. (The forms of energy are
interconvertible.)
โ€ข Think of a cyclist poised at the top of a hill.
Because of the attractive force of gravity,
the potential energy of the cyclist and her
bicycle is greater at the top of the hill than
at the bottom. As a result, the bicycle easily
moves down the hill with increasing speed. As
it does so, potential energy is converted into
kinetic energy. Potential energy decreases
as the bicycle rolls down the hill, but its
kinetic energy increases as the speed
increases.
The potential energy initially stored in the motionless bicycle and rider
at the top of the hill is converted to kinetic energy as the bicycle
moves down the hill and loses potential energy.
Chemical Energy
- the energy that is released during a chemical reaction or
change
- energy is required to bond atoms together and energy is
released when these bonds are broken
- can also be viewed as energy that is stored in some kind of
chemical substance
- energy is released when these substances mix together to
cause a chemical reaction
- during photosynthesis, plants convert light energy coming
from the sun into chemical energy
Module 1: Work, Mechanical Energy and Heat
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Module 1 / First Semester

Ms. Ma. Junallie E. Fuentebella-Pomperada

WORK, MECHANICAL ENERGY AND HEAT

Energy โ€“ capacity to do work or transfer heat Work โ€“ the energy used to cause an object to move against a force Heat โ€“ energy used to cause the temperature of an object to increase WORK

  • a scalar quantity (do not have directions)
  • defined and measured by the product of the net force exerted and the distance through which force moves Formula: ๐‘พ = ๐‘ญ๐’…๐’„๐’๐’”๐œฝ

where W = work

F = force

d = displacement

๐œƒ = angle between the force and the

direction of motion

Joule (J) โ€“ common unit for work Conversion: ๐Ÿ๐‘ฑ = ๐‘ต โˆ™ ๐’Ž or ๐Ÿ๐‘ฑ = ๐Ÿ ๐’Œ๐’ˆ โˆ™ ๐’Ž/๐’Ž โˆ™ ๐’”๐Ÿ MECHANICAL ENERGY

  • the sum of an objectโ€™s kinetic and potential energy KINETIC ENERGY
  • known as โ€œenergy of motionโ€
  • the KE of a body is dependent on its mass and speed Formula: ๐‘ฒ๐‘ฌ = ๐Ÿ^ ๐Ÿ โ„ ๐’Ž๐’—๐Ÿ where KE = Kinetic Energy m = mass v = speed Note:
  1. The kinetic energy of a body increases as its speed increases. Kinetic Energy (KE) is directly proportional to Speed (v).
  • A ball rolling at 10m/s has greater kinetic energy than it does at 5 m/s.
  1. For given speed, the kinetic energy increases with increasing mass.
  • A large truck traveling at 50 km/h has greater kinetic energy than a small car traveling at the same speed because the truck has the greater mass. Joule (J) โ€“ common unit for Kinetic Energy (KE) Potential Energy
  • known as โ€œ energy due to positionโ€
  • an object has potential energy by virtue of its position relative to other objects
  • in essence, the โ€œstoredโ€ energy that arises from the attractions and repulsions an object experiences in relation to other objects Formula: ๐‘ท๐‘ฌ = ๐’Ž๐’ˆ๐’‰ where PE = potential energy m = mass g = gravitational acceleration (9.8 m/s^2 ) h = height Joule (J) โ€“ common unit for Potential Energy (PE) Note:
  1. Potential energy may be converted into kinetic energy and vice versa. (The forms of energy are interconvertible.)
  • Think of a cyclist poised at the top of a hill. Because of the attractive force of gravity, the potential energy of the cyclist and her bicycle is greater at the top of the hill than at the bottom. As a result, the bicycle easily moves down the hill with increasing speed. As it does so, potential energy is converted into kinetic energy. Potential energy decreases as the bicycle rolls down the hill, but its kinetic energy increases as the speed increases. The potential energy initially stored in the motionless bicycle and rider at the top of the hill is converted to kinetic energy as the bicycle moves down the hill and loses potential energy. Chemical Energy
  • the energy that is released during a chemical reaction or change
  • energy is required to bond atoms together and energy is released when these bonds are broken
  • can also be viewed as energy that is stored in some kind of chemical substance
  • energy is released when these substances mix together to cause a chemical reaction
  • during photosynthesis, plants convert light energy coming from the sun into chemical energy

Module 1 : Work, Mechanical Energy and Heat

Module 1 / First Semester

Ms. Ma. Junallie E. Fuentebella-Pomperada Electromagnetic Energy

  • form of energy that is reflected or emitted from objects in the form of electrical and magnetic waves than can travel through space
  • may be viewed as moving electric charges Examples:
  • Power lines carry electricity
  • Electric motors are driven by electromagnetic energy
  • Light o a form of electromagnetic energy o each color of light (ROYGBIV) represents a different amount of electromagnetic energy
  • also carried by X-rays, radio waves, and laser light Nuclear Energy
  • the energy released during nuclear fission or fusion of nuclear energy a. Fission โ€“ happens when the nucleus splits and nuclear energy is released in the form of light and energy b. Fusion โ€“ when nuclei collide at high speeds and join, and nuclear energy is also released LAW OF CONSERVATION OF ENERGY
  • Energy cannot be created nor destroyed
  • It is simply transformed from one form into another In 1905
  • Albert Einstein proposed that mass and energy can be converted into each other
  • he showed that if matter is destroyed, energy is created and if energy is destroyed, mass is created. As the ball bounces up, it gains potential energy. At the highest point, the ball gains the maximum potential energy until it starts to fall. As the ball falls from its highest point, potential energy is converted to kinetic energy. As the ball falls, potential energy decreases but the speed of the ball increases, thus, kinetic energy increases. Just before the ball falls to the ground and stops, all of the potential energy has been converted into kinetic energy, and the ball gains its maximum velocity. If you may notice also, as the ball continues to bounce, the height that it reaches diminishes. Such happens because as the ball falls to the ground, sound is created. And so, some of the mechanical energy has been converted into sound energy. Other examples of energy conversion:
  1. The sunโ€™s energy through solar cells can be converted directly into electricity. o The solar cells (nonmechanical device) capture and store the energy from the direct sunlight, and is directed through an external load, such as a battery, that converts the solar energy into electrical energy and distribute it to the different electrical or power grid.
  2. Green plants convert the sunโ€™s energy (electromagnetic) into starches and sugars (chemical energy).
  3. In an automobile engine, fuel is burned to convert chemical energy into heat energy. The heat energy is then changed into mechanical energy.
  • the transfer of thermal energy from one object to another because of a temperature difference
  • always flows spontaneously from hot objects to cold objects (high temperature to low temperature)
  • it is not a form of matter Note:
  1. Temperature and heat are not the same.
  • Temperature โ€“ the average kinetic energy of all the particles in a substance
  • tells us whether something is hot or cold UNITS OF HEAT: a. Calorie (cal) โ€“ the amount of heat required to raise the temperature of one gram of water by one Celsius degree b. British Thermal Unit (BTU) โ€“ the amount of heat required to raise the temperature of one pound of water by one Fahrenheit degree c. Joule (J) โ€“ shows the relationship between energy in the form of work and energy in the form of heat known as the mechanical equivalent of heat Conversion Factors
  • 1 kcal = 1000 cal
  • 1 BTU = 252 cal
  • 1 BTU = 778 ft โ€“ lbf
  • 1 cal = 4.186 J KINDS OF HEAT a. Sensible Heat b. Latent Heat Sensible Heat
  • the amount of heat required to change temperature of the substance without changing its phase Example: a. Heating water at 25^0 C to 78^0 C at normal atmospheric conditions o Only the temperature of the water changed but it is still in the liquid phase Formula: ๐‘ธ = ๐’Ž๐‘ช๐’‘โˆ†๐‘ป where Q = sensible heat m = mass Cp = specific heat capacity (dependent on the material) โˆ†T = change in temperature (โˆ†T = Tfinal โ€“ Tinitial) Note:
  1. Specific heat is the ratio of the heat transferred to the corresponding rise in its temperature.
  2. Different substances have different capacities for storing heat.
  3. Different materials require different quantities of heat to raise the temperature through a specified number of degrees.
  4. The value of the specific heat varies for different materials as different materials absorb energy in different ways. SPECIFIC HEAT CAPATIES OF DIFFERENT SUBSTANCES

HEAT

Module 1 / First Semester

Ms. Ma. Junallie E. Fuentebella-Pomperada o Latent Heat

  1. Q 4 = Liquid โ€“ vapor o Boiling Point (100^0 C) o Latent Heat
  2. Equilibrium to Q 4 = Temperature transition but the phase remains the same (Vapor) o Sensible Heat
  3. Q 5 = superheated vapor o Sensible Heat Water
  • has a high boiling point because of the strong hydrogen bonds between the water molecules
  • it is both a strong hydrogen bond donor and acceptor Melting
  • first change of phase
  • the temperature stays the same while water melts Boiling
  • second change of phase
  • the temperature stays the same during the transition to gas ๐‘ธ๐’•๐’๐’•๐’‚๐’ = ๐‘ธ๐Ÿ + ๐‘ธ๐Ÿ + ๐‘ธ๐Ÿ‘ + ๐‘ธ๐Ÿ’ + ๐‘ธ๐Ÿ“ Q 1 (Sensible Heat) Equation: ๐‘ธ๐Ÿ = ๐’Ž๐‘ช๐’‘๐’Š๐’„๐’† โˆ†๐‘ป Q 2 (Latent Heat) Equation: ๐‘ธ๐Ÿ = ๐’Ž๐‘ฏ๐’‡ Q 3 (Sensible Heat) Equation: ๐‘ธ๐Ÿ‘ = ๐’Ž๐‘ช๐’‘๐’˜๐’‚๐’•๐’†๐’“ โˆ†๐‘ป Q 4 (Latent Heat) Equation: ๐‘ธ๐Ÿ’ = ๐’Ž๐‘ฏ๐’† Q 3 (Sensible Heat) Equation: ๐‘ธ๐Ÿ“ = ๐’Ž๐‘ช๐’‘๐’”๐’•๐’†๐’‚๐’Ž โˆ†๐‘ป Additional Notes: Melting
  • also known as fusion
  • temperature is constant
  • average kinetic energy of the particles is not changing
  • Superheating: when the substance is heated above its boiling point, but boiling does not occur Freezing
  • also known as crystallization
  • temperature is constant
  • average kinetic energy of the particles is not changing
  • Supercooling: when the substance is cooled below its freezing point, but freezing does not occur