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Thermochemistry Exercises: Enthalpy, Heat Capacity, and Calorimetry, Lecture notes of Chemistry

chemistry lecture notes atılım university

Typology: Lecture notes

2020/2021

Uploaded on 01/31/2021

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Recitation for Chapter 5
1) The value of ∆H° for the reaction below is -126 kJ. _________kJ are released when 2.00 mol of NaOH is
formed in the reaction? 63
2 2 2 2
2Na O (s) + 2H O (l) 4NaOH (s) + O (g)
2) The value of ∆H° for the reaction below is -126 kJ. The amount of heat that is released by the reaction
of 25.0 g of
2 2
Na O
with water is __________ kJ. 20.2
2 2 2 2
2Na O (s) + 2H O (l) 4NaOH (s) + O (g)
3) The value of ∆H° for the reaction below is -6535 kJ. __________ kJ of heat are released in the combustion
of 16.0 g of
6 6
C H (l)
?673
6 6 2 2 2
2C H (l) + 15O (g) 12CO (g) + 6H O (l)
4) The molar heat capacity of a compound with the formula
2 6
C H SO
is 88.0 J/mol-K. The specific heat of this
substance is __________ J/g-K. 1.13
5) The temperature of a 15-g sample of lead metal increases from 22°C to 37°C upon the addition of 29.0 J of
heat. The specific heat capacity of the lead is __________ J/g-K. 0.13
6) The ∆H for the solution process when solid sodium hydroxide dissolves in water is 44.4 kJ/mol. When a
13.9-g sample of NaOH dissolves in 250.0 g of water in a coffee-cup calorimeter, the temperature increases from
23.0°C to ________°C. Assume that the solution has the same specific heat as liquid water, i.e., 4.18 J/g-K.
37.0°C
7) ∆H for the reaction
5 3 2
IF (g) IF (g) + F (g)
is __________ kJ, give the data below. +355
2 3
IF (g) + F (g) IF (g) H = -390 kJ
2 5
IF (g) + 2F (g) IF (g) H = -745 kJ
8) Calculate ∆H° (in kJ) for reaction 3.
2 3
J
2 2
S (s) + O (g) SO (g) H = -297
kJ
the enthalpy of the reaction in which sulfur dioxide is oxidized to sulfur trioxide
2SO
2
(g) + O
2
(g) → 2SO
3
(g)
is __________ kJ. -196
9) The value of ∆H° for the reaction below is -186 kJ.
2 2
H (g) + Cl (g) 2HCl (g)
The value of
o
f
∆H
for HCl (g) is __________ kJ/mol. -93.0
10) Which one of the following is an exothermic process?
A) ice melting
B) water evaporating
C) boiling soup
D) condensation of water vapor
E) Ammonium thiocyanate and barium hydroxide are mixed at 25°C: the temperature drops.
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  1. The value of ∆H° for the reaction below is -126 kJ. _________kJ are released when 2.00 mol of NaOH is Recitation for Chapter 5 formed in the reaction? 63 2Na O 2 2 (s) + 2H O (l) 2 →4NaOH (s) + O 2 (g)

  2. The value of ∆H° for the reaction below is -126 kJ. The amount of heat that is released by the reaction of 25.0 g of Na O 2 2 with water is __________ kJ. 20. 2Na O 2 2 (s) + 2H O (l) 2 →4NaOH (s) + O 2 (g)

  3. The value of ∆H° for the reaction below is -6535 kJ. __________ kJ of heat are released in the combustion of 16.0 g of C H 6 6 (l)? 2C H 6 6 (l) + 15O 2 (g) →12CO 2 (g) + 6H O (l) 2

  4. The molar heat capacity of a compound with the formula C H SO 2 6 is 88.0 J/mol-K. The specific heat of this substance is __________ J/g-K. 1.

  5. The temperature of a 15-g sample of lead metal increases from 22°C to 37°C upon the addition of 29.0 J of heat. The specific heat capacity of the lead is __________ J/g-K. 0.

  6. The ∆H for the solution process when solid sodium hydroxide dissolves in water is 44.4 kJ/mol. When a13.9-g sample of NaOH dissolves in 250.0 g of water in a coffee-cup calorimeter, the temperature increases from 23.0°C to ________°C. Assume that the solution has the same specific heat as liquid water, i.e., 4.18 J/g-K. 37.0°C7) ∆H for the reaction

is __________ kJ, give the data below. +355IF^5 (g)^ →IF^3 (g) + F^2 (g) IF (g) + F 2 (g) → IF 3 (g) ∆H = -390 kJ IF (g) + 2F 2 (g) → IF 5 (g) ∆H = -745 kJ

  1. Calculate ∆H° (in kJ) for reaction 3. 2S (s) + 3O 2 (g) → 2SO 3 (g) ∆H = -790 kJ

the enthalpy of the reaction in which sulfur dioxide is oxidized to sulfur trioxideS (s) + O^2 (g)^ →^ SO^2 (g)^ ∆H = -297^ kJ 2SO 2 (g) + O 2 (g) → 2SO 3 (g) is __________ kJ. -

  1. The value of ∆H° for the reaction below is -186 kJ. H 2 (g) + Cl 2 (g) →2HCl (g)

The value of ∆H (^) fofor HCl (g) is __________ kJ/mol. -93.

  1. Which one of the following is an exothermic process?A) ice melting B) water evaporating C) boiling soup D) condensation of water vapor E) Ammonium thiocyanate and barium hydroxide are mixed at 25°C: the temperature drops.
  1. For which one of the following reactions is ∆H° (^) rxn equal to the heat of formation of the product? A) N 2 (g) + 3H 2 (g) →2NH 3 (g) B) (1/2)N 2 (g) + O 2 (g) →NO 2 (g) C) 6C (s) + 6H (g) →C H 6 6 (l)

D) P (g) + 4H (g) + Br (g) →PH Br (l) 4 E) 12C (g) + 11H 2 (g) + 11O (g) →C H 6 22 O 11 (g)

  1. For which one of the following reactions is the value of ∆H° (^) rxnequal to ∆H (^) fofor the product? A) 2Ca (s) + O 2 (g) →2CaO (s) B) C H 2 2 (g) + H 2 (g) →C H 2 4 (g) C) 2C (graphite) + O 2 (g) →2CO (g)

D) 3Mg (s) + N 2 (g) →Mg N 2 2 (s) E) C (diamond) + O 2 (g) →CO 2 (g)

  1. Given the data in the table below, ∆H° (^) rxnfor the reaction

is __________ kJ. -492.6C H OH (l) + O^2 5 2 (g)^ →CH CO H (l) + H O (l)^3 2

Substance ∆Η of (kJ/mol)

C 2 H 4 (g) 52. C CH 2 H 5 OH(l) -277. H 2 O(l)^3 CO 2 H(l)^ -484.5-285.

  1. Given the data in the table below, ∆H°rxn for the reaction

is __________ kJ. -11724NH^3 (g) + 5O^2 (g)^ →4NO (g) + 6H O (l)^2

Substance ∆Η of (kJ/mol)

H NO(g) 2 O(l) -286 90 NO 2 (g) 34 HNO NH 3 (aq) - 3 (g)^ -

  1. The units of of heat capacity are __________. J/K or J/°C
  2. When 0.800 grams of NaOH is dissolved in 100.0 grams of water, the temperature of the solution increases from 25.00 oC to 27.06 oC. The amount of heat absorbed by the water is __________ J. (The specific heat of water is 4.18 J/g - oC.) 861
  3. Given the equation: CH4 (g) + 2 O2 (g) → CO2 (g) + H2O (l) △H = -890 kJ The heat liberated when 34.78 grams of methane (CH4) are burned in an excess amount of oxygen is __________ kJ. 1930
  4. The combustion of titanium with oxygen produces titanium dioxide: Ti (s) + O 2 (g) →TiO 2 (s) When 0.721 g of titanium is combusted in a bomb calorimeter, the temperature of the calorimeter increases from25.00°C to 53.80°C. In a separate experiment, the heat capacity of the calorimeter is measured to be 9.84 kJ/K.

The heat of reaction for the combustion of a mole of Ti in this calorimeter is __________ kJ/mol. -1.49 × 104

  1. A 5.00-g sample of liquid water at 25.0 C is heated by the addition of 84.0 J of energy. The final temperature of the water is __________ °C. The specific heat capacity of liquid water is 4.18 J/g-K.29.
  2. A coffee cup calorimeter contains 525.0 grams of water at 25.0 ºC and 350.0 grams of water at 48.3 ºC isadded to it. Neglect the heat absorbed by the styrofoam, and calculate the final temperature. (The specific heat of water is 4.184J/g-degree.)34.3 ºC
  3. A calorimeter has a heat capacity of 3252.4 J/ ºC and at 24.50 ºC. Adding a piece of metal weighs 450 g, at 240.0 ºC caused the temperature to rise to 32.5 ºC. Find the specific heat of the metal.0.278 J /g- ºC