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A comprehensive overview of the properties, structure, and classification of metals. It delves into the crystalline structure of metals, explaining how their atomic arrangement influences their properties. The document then classifies metals into ferrous and non-ferrous categories, outlining the characteristics and applications of each type. It also explores the relationship between structure and properties in non-ferrous metals, highlighting the importance of alloying for specific applications.
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Title of the Module
Learning Objectives At the end of this module, the student shall be able: a. To distinguish different types of fuels. b. To calculate the amount of energy that can be derived from fuels. Content I. Structure of Metals II. Properties of Metals III. Classification of Metals Introduction Metals, from the Greek word ‘’metallon” (mine or quarry), are used in various aspects of our daily lives. Roughly 25% of the earth’s crust is comprised of metals and due to this abundance and metals’ varied properties, they can be used in construction, home appliances, tools, decorative items and jewelry, coinage and more. The history of refined metals is very long. The smelting and use of copper has been show to date back to the Bronze age, at around 3500 B.C. Gold, silver, meteoric iron, and lead have been in use earlier than that. The smelting of iron dates back to around 1500 B.C. and subsequent developments of early forms of steel followed at around 1200 B.C. Further discoveries of new types of metals and the development of modern alloys from early simple steel alloys to more complicated and specialized ones have happened over the years, to cater to various needs and applications. I. Structure of Metals Almost all metallic elements are crystalline solids at room temperature. Only cesium, gallium and mercury are not (with mercury being the only metal that is not solid at room temp.). This means that atoms of metals and metallic substances are arranged in an orderly and regular fashion. Imagine the metal atoms to be identical spheres which are stacked together in layers, each layer’s spheres slotting into the spaces between where the spheres of the other layers come together, much like how fruits are stacked in displays or how balls and cannonballs are stacked together.
Figure 1. metal atoms are stacked similarly to how we see fruit being stacked or how any large or heavy spheres are stored/arranged This arrangement is the most efficient as it minimizes the empty space between the spheres. Metal crystals have unit cells – the smallest section of a crystal lattice that still retails the overall structure and symmetry of the lattice – wherein the atoms are arranged in such close-packed structures. Most pure metals and metallic alloys naturally adopt one of these three arrangements which provide the closest packing structures: www.ggspdt.com Figure 2. The common structures of the unit cells of most metals (a) Hexagonal close-packed (hcp) structure. This crystal structure has atoms occupying all corners of a hexagonal prism and one atom at the center of each of the two hexagonal faces. (b) Face-centered cubic (fcc) structure. In this structure, there is one atom at the center of each of the six faces of the cube and eight atoms at each corner. (c) Body-centered cubic (bcc) structure. In this crystal structure, we can imagine eight of the metal atoms occupying all corners of a cube and another atom at the very center of the cube. These different structures affect certain metallic behaviors particularly strength and ductility. Because of the close-packed nature of the atoms, the attraction between the atomic nuclei and the surrounding electrons may occur in all directions and we can say that the bonding in metals in nondirectional; this means that upon the application of pressure, a metal will deform rather than
the BCC structure. Figure 4. How metallic crystal structure affects ductility III. Classification of Metals Ferrous vs. Nonferrous Metals This is the most general/broad classification of metals. Ferrous metals, as the name implies, contain iron (“ ferrum ” being the Latin name for iron). Iron (Fe) is a very abundant element and although difficult to find pure in nature, it is present in many minerals. It is also relatively cheap due to the fact that it is relatively easy to refine. When combined with other metals in alloys, or even by itself, it displays different properties which results in its versatility as an alloying component. Ferrous metals are also magnetic and strong but are prone to corrosion. Around 90% of all manufactured metals contain iron. Non- ferrous metals, like brass, on the other hand do not have iron in them. They do not have any magnetic properties. The most common non-ferrous metals used in the industry are Cu, Al, Zn, Sn, Pb, Co, and Ni. The non-ferrous metals and the alloys based on them have names that are based on their element’s names (e.g. copper alloy, aluminum alloy, etc.) FERROUS METALS Properties Uses Pig Iron/Crude Iron (92%iron, up to 3.5% C and other impurities)
a bit brittle Wrought Iron (iron with less than 0.08% C)