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A comprehensive overview of ionic liquids, a unique class of solvents with remarkable properties and a wide range of applications. It covers the history, characteristics, and functionality of ionic liquids, highlighting their potential as designer solvents. The document delves into various applications, including organic reactions, bioscience (biorefinery), and supported ionic liquid phase (silp) catalysis. It showcases the tunability of ionic liquids, their ability to overcome limitations of traditional solvents, and their growing importance in scientific and technological advancements. The detailed information presented in this document makes it a valuable resource for researchers, students, and professionals interested in exploring the versatility and potential of ionic liquids.
Typology: Lecture notes
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Ionic Liquids are ionic compounds(salts) whichare liquid below 100
℃
. More commonly,
Ionic Liquids have melting points below roomtemperature.
DSC (Differential Scanning Calorimetry)
②
liquid
glass
m.p.
Supercooling
liquid
Phase transition is hard to happen.
Flexibility of the constituent ions
Conformational diversity
http://ilthermo.boulder.nist.gov/ILThermo/pureils.uix.do?event=NewSearch
http://ilthermo.boulder.nist.gov/ILThermo/pureils.uix.do?event=NewSearch
Organic Reaction (TEMPO oxidation)
①
Organic Reaction (TEMPO oxidation)
②
R. Gree,
et al. Org. Lett